It seems Orange in Romania is the first one to put up the new Samsung Galaxy S5 for pre-order. The phone is available with a 2-year contract for €249 or you can pay €699 and get the phone without a contract and also completely unlocked. Orange will also throw in an S-View Flip Cover for the S5.
You can find the link to purchase the phone below.
Orange Romania (Thanks Ioansuhov for the tip)DOWNLOAD CENTER >>Cynogenmod 11,ROM.ZIP(KITKAT) ,ROM.ZIP(JELLYBEAN),ALL USB DRIVER